超清版 GB/T 44242-2024 质子交换膜燃料电池汽车用氢气 无机卤化物、甲酸的测定 离子色谱法
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- 更新时间：2025-03-19
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资料介绍
ICS 27.010
CCS F 19
GB/T 44242—2024
质子交换膜燃料电池汽车用氢气
无机卤化物、甲酸的测定 离子色谱法
Hydrogen for proton exchange membrane fuel cell vehicles—Determination of
inorganic halogenated compounds and formic acid—Ion chromatography
method
2024⁃07⁃24 发布2024⁃11⁃01 实施
国家市场监督管理总局
国家标准化管理委员会发 布
目 次
前言··························································································································Ⅲ
1 范围·······················································································································1
2 规范性引用文件········································································································1
3 术语和定义··············································································································1
4 原理·······················································································································1
5 试剂与材料··············································································································2
6 仪器和设备··············································································································2
7 试验步骤·················································································································3
8 试验数据处理···········································································································4
9 精密度····················································································································5
10 质量保证和控制······································································································6
11 试验报告···············································································································7
附录A（ 资料性） 离子色谱操作条件和淋洗液洗脱程序、标准色谱图和校准曲线·························8
参考文献····················································································································10
前 言
本文件按照GB/T 1.1—2020《标准化工作导则 第1 部分：标准化文件的结构和起草规则》的规
定起草。
请注意本文件的某些内容可能涉及专利。本文件的发布机构不承担识别专利的责任。
本文件由全国氢能标准化技术委员会（SAC/TC 309）提出并归口。
本文件起草单位：中石化石油化工科学研究院有限公司、中国标准化研究院、山西省检验检测中心
（山西省标准计量技术研究院）、中国计量科学研究院、四川中测标物科技有限公司、北京博赛德科技有
限公司、中石化（大连）石油化工研究院有限公司、丰田智能电动汽车研发中心（中国）有限公司、清华大
学、北京国氢中联氢能科技研究院有限公司、青岛盛瀚色谱技术有限公司、劢强科技（上海）有限公司、
赛默飞世尔科技（中国）有限公司北京分公司、岛津企业管理（中国）有限公司、国家能源集团氢能科技
有限责任公司、氢迹技术（上海）有限公司。
本文件主要起草人：万伟、刘雅琼、徐广通、杨燕梅、王亚敏、胡树国、程建山、张鹏辉、任文华、王少军、
郝逍瑶、周鲁立、杜利锋、王艮成、韩强、万燕鸣、刘聪敏、朱玮郁、侯方烁、李致伯、姜振邦、王惠玉。
警示：氢气是一种易燃易爆气体。本文件不涉及与其应用有关的所有安全问题。在使用本文件
前，使用者有责任制定相应的安全和保护措施，明确其限定的适用范围，并保证符合国家有关法律法
规、强制性国家标准的规定。
1 范围
本文件描述了采用离子色谱法测定质子交换膜燃料电池汽车用氢气中无机卤化物、甲酸含量的原
理、试剂和材料、仪器和设备、试验步骤、试验数据处理、精密度、质量保证和控制、试验报告。
本文件适用于质子交换膜燃料电池汽车用氢气中无机卤化物、甲酸含量的测定，其他用途氢气中
无机卤化物、甲酸含量的测定参照执行。氢气中无机卤化物、甲酸含量的测定范围为0.025 μmol/mol~
0.5 μmol/mol，氢气中氯化氢、氯气、溴化氢、甲酸组分的检出限分别为0.014 μmol/mol、0.007 μmo
CCS F 19
GB/T 44242—2024
质子交换膜燃料电池汽车用氢气
无机卤化物、甲酸的测定 离子色谱法
Hydrogen for proton exchange membrane fuel cell vehicles—Determination of
inorganic halogenated compounds and formic acid—Ion chromatography
method
2024⁃07⁃24 发布2024⁃11⁃01 实施
国家市场监督管理总局
国家标准化管理委员会发 布
目 次
前言··························································································································Ⅲ
1 范围·······················································································································1
2 规范性引用文件········································································································1
3 术语和定义··············································································································1
4 原理·······················································································································1
5 试剂与材料··············································································································2
6 仪器和设备··············································································································2
7 试验步骤·················································································································3
8 试验数据处理···········································································································4
9 精密度····················································································································5
10 质量保证和控制······································································································6
11 试验报告···············································································································7
附录A（ 资料性） 离子色谱操作条件和淋洗液洗脱程序、标准色谱图和校准曲线·························8
参考文献····················································································································10
前 言
本文件按照GB/T 1.1—2020《标准化工作导则 第1 部分：标准化文件的结构和起草规则》的规
定起草。
请注意本文件的某些内容可能涉及专利。本文件的发布机构不承担识别专利的责任。
本文件由全国氢能标准化技术委员会（SAC/TC 309）提出并归口。
本文件起草单位：中石化石油化工科学研究院有限公司、中国标准化研究院、山西省检验检测中心
（山西省标准计量技术研究院）、中国计量科学研究院、四川中测标物科技有限公司、北京博赛德科技有
限公司、中石化（大连）石油化工研究院有限公司、丰田智能电动汽车研发中心（中国）有限公司、清华大
学、北京国氢中联氢能科技研究院有限公司、青岛盛瀚色谱技术有限公司、劢强科技（上海）有限公司、
赛默飞世尔科技（中国）有限公司北京分公司、岛津企业管理（中国）有限公司、国家能源集团氢能科技
有限责任公司、氢迹技术（上海）有限公司。
本文件主要起草人：万伟、刘雅琼、徐广通、杨燕梅、王亚敏、胡树国、程建山、张鹏辉、任文华、王少军、
郝逍瑶、周鲁立、杜利锋、王艮成、韩强、万燕鸣、刘聪敏、朱玮郁、侯方烁、李致伯、姜振邦、王惠玉。
警示：氢气是一种易燃易爆气体。本文件不涉及与其应用有关的所有安全问题。在使用本文件
前，使用者有责任制定相应的安全和保护措施，明确其限定的适用范围，并保证符合国家有关法律法
规、强制性国家标准的规定。
1 范围
本文件描述了采用离子色谱法测定质子交换膜燃料电池汽车用氢气中无机卤化物、甲酸含量的原
理、试剂和材料、仪器和设备、试验步骤、试验数据处理、精密度、质量保证和控制、试验报告。
本文件适用于质子交换膜燃料电池汽车用氢气中无机卤化物、甲酸含量的测定，其他用途氢气中
无机卤化物、甲酸含量的测定参照执行。氢气中无机卤化物、甲酸含量的测定范围为0.025 μmol/mol~
0.5 μmol/mol，氢气中氯化氢、氯气、溴化氢、甲酸组分的检出限分别为0.014 μmol/mol、0.007 μmo