铁磁性和铁混合价在2d光诱导的效果
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- 标准类型：钢铁冶金
- 标准语言：中文版
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- 更新时间：2016-01-27
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资料介绍
Iron mixed-valence complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto =C2O2S2), shows a
spin-entropy driven phase transition called charge transfer
phase transition around 120K and a ferromagnetic transition at 6.5 K. These phase
transitions remarkably depend on the hexagonal ring size in
two-dimensional honeycomb network structure of [FeIIFeIII(dto)3]∞. In order to
control the magnetic properties and the electronic state in the
dto-bridged iron mixed-valence system by means of photo-irradiation, we have
synthesized a photo-sensitive organic